推荐教材

“Spectroscopic Methods in Organic Chemistry”, by Dudley Williams and Ian Fleming, 2007, 6th edition.

  

This book is the sixth edition of a well-established introductory guide to the interpretation of the ultraviolet, infrared, nuclear magnetic resonance and mass spectra of organic compounds. It is a textbook satiable for a first course in the application of these techniques to structure determination, and as a handbook for organic chemists to keep on their desks throughout their career.

There four spectroscopic methods have been used routinely for several decades to determine the structure of organic compounds, both those isolated from natural sources. Every organic chemist needs to be skilled in how to apply them, and to known which method words for which problem. In outline, the ultraviolet spectrum identifies conjugated systems, the infrared spectrum identifies functional groups, the nuclear magnetic resonance spectra identify how the atoms are connected, and the mass spectrum gives the molecular formula. One or more of these techniques nowadays is very frequently enough to identify the complete chemical structure of an unknown compound, or to confirm the structure of a known compound. If they are not enough on their own, there are other methods that the organic chemist can turn to: X-ray diffraction, microwave absorption, the Raman spectrum, electron spin resonance and circular dichroism, among others. Powerful though they are, these techniques are all more specialised, and less part of the everyday practice of most organic chemists.

We have kept discussion of the theoretical background to a minimum, since application of the spectroscopic methods is possible without a detailed command of the theory behind them. We have described instead how the techniques work, and how to read each of the four kinds of spectra, including each of the most important 2D NMR spectra. We have included many tables of data at the ends of chapters 2, 3 and 4, all of which are needed in the day-to-day interpretation of spectra. Finally in Chapter 5, we work through 11 examples of the way in which the four spectroscopic methods can be for you to work through for practice.

In preparing a sixth edition, we have almost completely rewritten the book, to reflect our experience teaching the subject, and to respond to changes that have taken place, both of emphasis and of fact, since the fifth edition was published. The chapter on MS made more specific to the everyday, rather than to the more specialised, applications of this technique. The appearance of IR absorptions, formerly gathered at the end of the chapter, is now illustrated at the relevant points in the text. Conversely, we have moved the tables of IR date to the end of the chapter, where they are more convenient for reference and match the arrangement we have always used for the NMR and MS chapters. Most significantly, we have replaced all of the 60 MHz spectra used hitherto to explain the fundamentals of NMR spectroscopy with new and carefully chosen examples at 400 MHz or more 2D NMR techniques. We have added a number of tables of basic NMR information-chemical shift and coupling constants-for the most common nuclei other than 1H and 13C; namely 11B, 15N, 19F, 29Si and 31P. Finally, all the spectra in the examples and problems in Chapter 5 have been redrawn, smaller, but with no loss of detail. In this way, all the spectra for each problem can be presented conveniently in portrait orientation, and on one page in most cases.

参考文献目录

参考书目录
综合参考图书

1.《仪器分析》孙凤霞主编 化学工业出版社 2004

2.《波谱分析教程》邓芹英等编著 科学出版社2003

3.《有机化合物波谱解析》姚新生主编 中国医药科技出版社 2004

4.《有机光谱分析》张正行主编 人民卫生出版社 1996

5.《有机结构波谱分析》李润卿主编 天津大学出版社 2002

6.电子图书http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/spectro.htm#contnt

7.电子图书http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/MassSpec/masspec1.htm

紫外—可见光谱(Ultraviolet and Visible Spectroscopy)参考图书:

1.Ultraviolet and Visible Spectroscopy: Analytical Chemistry by Open Learning by Michael J. K. Thomas and David J. Ando (1996)

2.Visible and Ultraviolet Spectroscopy (Analytical Chemistry By Open Learning) by Ronald C. Denney, Roy Sinclair, and David Mowthorpe (1987)

3.Ultraviolet & visible spectroscopy, series 7000: Supplementary notes & exercises, programs 7004, 7005, 7006 by Brian Howard (1976)

4.Ultraviolet and Visible Spectroscopy (Analytical Chemistry By Open Learning (Series).) by Michael J. K. Thomas and D. J. Ando (1997)

红外光谱(Infrared spectroscopy)参考图书:

1.IR Spectroscopy: An Introduction by Helmut Günzler and Hans-Ulrich Gremlich (2002)

2.Biological Applications of Infrared Spectroscopy by Barbara H. Stuart and David J. Ando (1997)

3.Infrared and Raman Spectroscopy of Biological Materials (Practical Spectroscopy) by Hans-Ulrich Gremlich and Bing Yan (2000)

4.Infrared Spectral Interpretation: A Systematic Approach by Brian C. Smith (1998)

核磁共振(Nuclear Magnetic ResonanceNMR)参考图书:

1.Nuclear Magnetic Resonance Spectroscopy: An Introduction to Principles, Applications, and Experimental Methods by Joseph B. Lambert and Eugene P. Mazzola (2003)

2.Nuclear Magnetic Resonance Spectroscopy by John H. Nelson (2002)

3.Nuclear Magnetic Resonance Spectroscopy in Environmental Chemistry (Topics in Environmental Chemistry) by Mark A. Nanny, Roger A. Minear, and Jerry A. Leenheer (1997)

4.Fundamentals of Nuclear Magnetic Resonance Spectroscopy by Robert, A. Izydore (2007)

质谱(Mass Spectrometry)参考图书:

1.Mass Spectrometry: Principles and Applications by Edmond de Hoffmann and Vincent Stroobant (2007)

2.Introduction to Mass Spectrometry: Instrumentation, Applications, and Strategies for Data Interpretation by J. Throck Watson and O. David Sparkman (2007)

3.The Expanding Role of Mass Spectrometry in Biotechnology, Second Edition by Gary Siuzdak (2006)

4.Mass Spectrometry and Hyphenated Techniques in Neuropeptide Research by Jerzy Silberring, Ralph Ekman, Dominic M. Desiderio, and Nico M. Nibbering (2002)

参考网站
紫外—可见光谱参考网站

1.http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng

2.http://www.chem.ucalgary.ca/courses/351/Carey/Ch13/ch13-uvvis.html

3.http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/UV-Vis/spectrum.htm

4.http://en.wikipedia.org/wiki/UV/VIS_spectroscopy

5.http://www.infochembio.ethz.ch/links/en/spectrosc_uvvis.html

6.http://www.geocities.com/CapeCanaveral/Lab/4433/Spectroscopy/UV-Vis/index.htm

7.http://www.chemistry.ccsu.edu/glagovich/teaching/316/uvvis/uvvis.html

8.http://www.globalspec.com/Industrial-Directory/spectroscopy_ultraviolet_visible

9.http://www.uio.no/studier/emner/matnat/kjemi/KJM-MEF4010/v06/moduler/UV_synlig.xml

10.http://www.imp.mtu.edu/matchar/uv.html

11.http://wps.prenhall.com/esm_bruice_organic_4/0,7842,742742-,00.html

12.http://www.chemistryexplained.com/Ru-Sp/Spectroscopy.html

13.http://www.azom.com/SearchResults.asp?AppKeyWord=Ultraviolet-visible+spectroscopy

14.http://www.brookscole.com/chemistry_d/templates/student_resources/shared_resources/act/spect/spec3.html

15.http://medlibrary.org/medwiki/Ultraviolet-visible_spectroscopy

红外光谱参考网站:

1.http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng

2.http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/InfraRed/infrared.htm

3.http://en.wikipedia.org/wiki/Infrared_spectroscopy

4.http://www.colby.edu/chemistry/JCAMP/IRHelper.html

5.http://webbook.nist.gov/chemistry/#Search

6.http://orgchem.colorado.edu/hndbksupport/irtutor/tutorial.html

7.http://www.wpi.edu/Academics/Depts/Chemistry/Courses/General/infrared.html

8.http://www.umsl.edu/~orglab/documents/IR/IR2.html

9.http://www.dq.fct.unl.pt/qoa/jas/ir.html

10.http://www.chemguide.co.uk/analysis/irmenu.html

11.http://www.cem.msu.edu/~parrill/AIRS/

12.http://www.chem.umass.edu/~nermmw/Spectra/irspectra/index.htm

13.http://www2.uj.edu.pl/RegLab/infrared/

14.http://pslc.ws/macrog/ir.htm

15.http://elchem.kaist.ac.kr/vt/chem-ed/spec/vib/nir.htm

核磁共振参考网站:

1.电子图书http://www.cis.rit.edu/htbooks/nmr/

2.电子图书http://www.chembio.uoguelph.ca/driguana/nmr/TOC.HTM

3.http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng

4.http://www.chemexper.com/

5.http://nmrshiftdb.ice.mpg.de/

6.http://teaching.shu.ac.uk/hwb/chemistry/tutorials/molspec/nmr1.htm

7.http://www.spectroscopynow.com/coi/cda/home.cda?chId=5

8.http://en.wikipedia.org/wiki/NMR_spectroscopy

9.http://www.spincore.com/nmrinfo/

10.http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/nmr/nmr1.htm

11.http://www.cryst.bbk.ac.uk/PPS2/projects/schirra/html/home.htm

12.http://www.cis.rit.edu/htbooks/nmr/inside.htm

13.http://www.acornnmr.com/

14.http://www.nmr.utmb.edu/

15.http://www.nmr.chem.uu.nl/Main/index.php

质谱参考网站:

1.http://riodb01.ibase.aist.go.jp/sdbs/cgi-bin/cre_index.cgi?lang=eng

2.http://www.colby.edu/chemistry/cmp/cmp.html

3.http://elchem.kaist.ac.kr/vt/chem-ed/spec/vib/nir.htm

4.http://en.wikipedia.org/wiki/Mass_spectrometry

5.http://www.astbury.leeds.ac.uk/facil/MStut/mstutorial.htm

6.http://www.cem.msu.edu/~reusch/VirtualText/Spectrpy/MassSpec/masspec1.htm

7.http://www.rsc.org/Publishing/CurrentAwareness/index.asp

8.http://www.ionsource.com/

9.http://www.chem.arizona.edu/massspec/

10.http://masspec.scripps.edu/redirect.html

11.http://www.spectroscopynow.com/coi/cda/home.cda?chId=4

12.http://www.asms.org/

13.http://www.chem.vt.edu/chem-ed/crossref/ac-mass-spec.html

14.http://www3.appliedbiosystems.com/applicationstechnologies/MassSpectrometry/index.htm

15.http://www.chemguide.co.uk/analysis/masspecmenu.html